3,3-Diethoxy-1-propanol → 3,3-Diethoxy-1-propanol

HRID 582798Notes

Reaction equation

HRID 582798 reaction equation
[CH2:1]([O:3][CH:4]([O:8][CH2:9][CH3:10])[CH2:5][CH2:6][OH:7])[CH3:2].C1C2C(=CC=CC=2)C=CC=1.[K:21]>O1CCCC1>[K:21].[CH2:1]([O:3][CH:4]([O:8][CH2:9][CH3:10])[CH2:5][CH2:6][OH:7])[CH3:2]

Participants

5

Reactant 2

HCID 1401353,3-Diethoxy-1-propanolHCID 66602812Naphthalene potassium

Product 2

HCID 1401353,3-Diethoxy-1-propanolHCID 5462222Potassium

Reagents, catalysts & solvents 1

HCID 8028TetrahydrofuranSolvent3×

Procedure

A reactor was charged with 30 ml of THF, 0.13 g of 3, 3-diethoxypropanol and 2 ml solution of potassium naphthalene dissolved in tetrahydrofuran in a concentration of 0.5 mol/L-tetrahydrofuran, and the resulting mixture was stirred for three minutes in an argon atmosphere, and, thus, there was formed a potassium derivative (potassium 3, 3-diethoxypropanoxide) of 3, 3-diethoxypropanol.

Sources & evidence

ORD record
ord-04bb0291bcd64345a483338c57e0abaa
Source dataset
uspto-grants-1999_07
Patent number
US05925720

Reaction notes

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