Ruthenium trichloride → HCID 86694788, compound

HRID 590589Notes

Reaction equation

HRID 590589 reaction equation
[C:1]1([C:7]2[CH:12]=[CH:11][CH:10]=[CH:9][CH:8]=2)[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1.[H-].[H-].[Ru:15]([Cl:18])([Cl:17])[Cl:16]>C(O)C>[Ru:15]([Cl:18])([Cl:17])[Cl:16].[C:1]1([C:7]2[CH:8]=[CH:9][CH:10]=[CH:11][CH:12]=2)[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1

Participants

4

Reactant 2

HCID 61850Ruthenium trichloride3×HCID 86694789HCID 86694789, compound4×

Product 1

HCID 86694788HCID 86694788, compound

Reagents, catalysts & solvents 1

HCID 702EthanolSolvent2×

Procedure

The reaction product mixture containing dihydride biphenyl is made to contact ruthenium chloride in ethanol, wherein, amount of the reaction product mixture containing dihydride biphenyl should be such that the molar ratio of dihydride biphenyl to ruthenium chloride is 5:1, the contacting temperature is 80° C., the contacting time is 8 hours. On the basis that the total weight of dihydride biphenyl and ruthenium chloride is 100 mg, 60 ml of ethanol should be used. The mixture is filtered and washed with methanol to obtain biphenyl ruthenium trichloride dimer.

Workup

  1. customis 80° C.
  2. filtrationThe mixture is filtered
  3. washwashed with methanol

Sources & evidence

ORD record
ord-e53f8d8e89ad4bf99e06c29a76e92d49
Source dataset
uspto-grants-2016_01
Patent number
US09233995B2

Reaction notes

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