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HRID591360

反应详情

EQUATION

反应方程式

HRID 591360 的结构方程式

REACTANTS

反应物

2
结构：C=CC(=O)OC
HCID7294

Methyl acrylate

C4H6O2

结构：F[B-](F)(F)F.N#[N+]c1ccc(S(F)(F)(F)(F)F)cc1
HCID122235275

未命名化合物

PRODUCTS

生成物

1
结构：COC(=O)/C=C/c1ccc(S(F)(F)(F)(F)F)cc1
HCID21576971

未命名化合物

AUXILIARIES

试剂、催化剂与溶剂

2
结构：CC(=O)[O-].CC(=O)[O-].[Pd+2]
催化剂HCID167845

Diacetatopalladium

C4H6O4Pd

结构：CCO
溶剂HCID702

Ethanol

C2H6O

PROCEDURE

实验过程

Diazonium salt 1 reacted with methyl acrylate in the presence of Pd(OAc)2 in 95% EtOH to give methyl trans-3-[4-(pentafluorosulfanyl)phenyl]prop-2-enoate 3 in 85% isolated yield with no cis isomer being observed, as seen in FIG. 2.