Hydrochloric Acid → HCID 21414243, compound

HRID 597672Notes

Reaction equation

HRID 597672 reaction equation
[CH3:1][N:2]([CH3:23])[CH2:3][CH2:4][O:5][N:6]=[C:7]1[C:13]2[CH:14]=[CH:15][CH:16]=[CH:17][C:12]=2[CH:11]2[CH2:18][CH:10]2[C:9]2[CH:19]=[CH:20][CH:21]=[CH:22][C:8]1=2.[ClH:24]>CCOCC>[ClH:24].[CH3:1][N:2]([CH3:23])[CH2:3][CH2:4][O:5][N:6]=[C:7]1[C:13]2[CH:14]=[CH:15][CH:16]=[CH:17][C:12]=2[CH:11]2[CH2:18][CH:10]2[C:9]2[CH:19]=[CH:20][CH:21]=[CH:22][C:8]1=2

Participants

4

Reactant 2

HCID 313Hydrochloric AcidHCID 21414233HCID 21414233, compound

Product 1

HCID 21414243HCID 21414243, compound

Reagents, catalysts & solvents 1

HCID 3283Diethyl EtherSolvent

Procedure

1,1a,6,10b-Tetrahydrodibenzo[a,e]cyclopropa[c]cyclohepten-6-one O-[2-(dimethylamino)ethyl]oxime prepared as in Example 1 was dissolved in ether and saturated with anhydrous hydrogen chloride. The precipitate was filtered and thoroughly washed with ether. The product was recrystallized from acetonitrile, and dried at 100° (0.1 mm), mp 169°-171° .

Workup

  1. filtrationThe precipitate was filtered
  2. washthoroughly washed with ether
  3. customThe product was recrystallized from acetonitrile
  4. customdried at 100° (0.1 mm), mp 169°-171°

Sources & evidence

ORD record
ord-eb4ff10fc5ed4ca1b18d5a8f0c561713
Source dataset
uspto-grants-1977_03
Patent number
US04014936

Reaction notes

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