Oxygen → Acetophenone

HRID 599720Notes

Reaction equation

HRID 599720 reaction equation
O=O.[C:3]1([CH:9]([OH:11])[CH3:10])[CH:8]=[CH:7][CH:6]=[CH:5][CH:4]=1>[Pt].O>[C:9]([C:3]1[CH:8]=[CH:7][CH:6]=[CH:5][CH:4]=1)(=[O:11])[CH3:10]

Participants

5

Reactant 2

HCID 977OxygenHCID 74091-Phenylethanol

Product 1

HCID 7410AcetophenoneYield 82%

Reagents, catalysts & solvents 2

HCID 23939PlatinumCatalystHCID 962WaterSolvent

Procedure

In an ambient pressure oxygen atmosphere, 121 μl of 1-phenyl ethanol and 173.7 mg of the platinum catalyst obtained in Example 1 were agitated for twenty-four hours at 60° C. in 10 ml of water. The reaction mixture was subsequently extracted using ethyl acetate, and the organic layer was dried using magnesium sulfate and filtered to obtain 98.9 mg (82% yield) of acetophenone. The reaction equation and the analytical results of the product are shown below.

Workup

  1. extractionThe reaction mixture was subsequently extracted
  2. customthe organic layer was dried
  3. filtrationfiltered

Sources & evidence

ORD record
ord-9343fef9a294494c9c4edbca096df93a
Source dataset
uspto-grants-2011_03
Patent number
US07897817B2

Reaction notes

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