Oxygen → 2-Octanone

HRID 599725Notes

Reaction equation

HRID 599725 reaction equation
O=O.[CH3:3][CH:4]([OH:11])[CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH3:10]>[Pt].O>[CH3:3][C:4](=[O:11])[CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH3:10]

Participants

5

Reactant 2

HCID 977OxygenHCID 200832-Octanol

Product 1

HCID 80932-OctanoneYield 85.3%

Reagents, catalysts & solvents 2

HCID 23939PlatinumCatalystHCID 962WaterSolvent

Procedure

In an ambient pressure oxygen atmosphere, 26.9 mg of 2-octanol and 35.3 mg of the platinum catalyst obtained in Example 1 were agitated for fifteen hours at 60° C. in 2 ml of water. The reaction mixture was subsequently extracted using ethyl acetate, and the organic layer was dried using magnesium sulfate, filtered and concentrated to obtain 22.6 mg (85% yield) of 2-octanone. The reaction equation and the analytical results of the product are shown below.

Workup

  1. extractionThe reaction mixture was subsequently extracted
  2. customthe organic layer was dried
  3. filtrationfiltered
  4. concentrationconcentrated

Sources & evidence

ORD record
ord-4de02a5225034cdd915e7df9d545ce58
Source dataset
uspto-grants-2011_03
Patent number
US07897817B2

Reaction notes

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