cis,cis-1,5-Cyclooctadiene → HCID 2733356, compound

HRID 600172Notes

Reaction equation

HRID 600172 reaction equation
[Pd:1]([Cl:3])[Cl:2].[Cl-].[Li+].[CH:6]1[CH2:13][CH2:12][CH:11]=[CH:10][CH2:9][CH2:8][CH:7]=1>CO>[Cl:2][Pd:1][Cl:3].[CH:6]1[CH2:13][CH2:12][CH:11]=[CH:10][CH2:9][CH2:8][CH:7]=1

Participants

5

Reactant 3

HCID 8135cis,cis-1,5-CyclooctadieneHCID 24290Palladium ChlorideHCID 433294Lithium Chloride

Product 1

HCID 2733356HCID 2733356, compoundYield 99.8%

Reagents, catalysts & solvents 1

HCID 887MethanolSolvent

Procedure

Palladium chloride (3.0 g; manufactured by Wako Pure Chemical Industry), 2.1 g of lithium chloride (manufactured by Wako Pure Chemical Industry) and 40 mL of methanol were charged in a flask made of glass where inner air was substituted with highly pure argon and were stirred for 4 hours. 1,5-Cyclooctadiene (2.31 g; manufactured by Wako Pure Chemical Industry) was added to the resulting homogeneous solution and the mixture was stirred for 12 hours. The resulting yellow solid was sucked to give 4.82 g of 1,5-cyclooctadiene dichloropalladium.

Workup

  1. stirringthe mixture was stirred for 12 hours

Sources & evidence

ORD record
ord-006232c63b264fab93bae3fa28a90104
Source dataset
uspto-grants-2011_03
Patent number
US07902109B2

Reaction notes

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