HRID607709

反应详情

EQUATION

反应方程式

HRID 607709 的结构方程式

REACTANTS

反应物

2

结构：COc1ccc(Cl)cc1

Benzene, 1-chloro-4-methoxy-

C7H7ClO

结构：Cc1cc(C)c(B(O)O)c(C)c1

2,4,6-Trimethylphenylboronic acid

C9H13BO2

PRODUCTS

生成物

1

结构：COc1ccc(-c2c(C)cc(C)cc2C)cc1

未命名化合物

AUXILIARIES

试剂、催化剂与溶剂

5

结构：O

Water

H2O

结构：O=P([O-])([O-])[O-].[K+].[K+].[K+]

试剂HCID62657

Tripotassium phosphate

K3O4P

$结构：C1=C\CC/C=C\CC/1.C1=C\CC/C=C\CC/1.[Ni]$

催化剂HCID6433264

未命名化合物

结构：CN(C)c1cccc(N(C)C)c1-c1ccccc1P(C1CCCCC1)C1CCCCC1

催化剂HCID44156169

2-(2-Dicyclohexylphosphanylphenyl)-1-N,1-N,3-N,3-N-tetramethylbenzene-1,3-diamine

C28H41N2P

结构：C1COCCO1

溶剂HCID31275

1,4-Dioxane

C4H8O2

CONDITIONS

反应条件

温度: 60 °C

PROCEDURE

实验过程

pre-ligate Ni(cod)2 and phosphine ligand in dioxane for 15 minutes in a separate plate

WORKUP

后处理

additionDilute with acetonitrile
aliquot未记录说明
customDiluent solution was made in 1 L batches with 950 mL acetonitrile, 25 mL water, 25 mL glacial acetic acid, and 53 mg 4,4’-di-tert-butylbiphenyl as an external standard (0.2 equiv standard per reaction). Aliquot taken from each well (47 ul) is added into 753 ul of diluent solution