Water → HCID 57285646, compound

HRID 610770Notes

Reaction equation

HRID 610770 reaction equation
S(OOS([O-])(=O)=O)([O-])(=O)=O.[K+].[K+].C(#N)C.[O:16]=[O+][O-].Cl.[NH2:20][C:21]12[CH:28]3[C:23]4(N)[CH:24]5[C:27]3(N)[CH:26]1[C:25]5(N)[CH:22]24.[OH2:32]>>[N+:20]([C:21]12[CH:28]3[CH:23]4[CH:24]5[CH:27]3[CH:26]1[CH:25]5[CH:22]24)([O-:16])=[O:32]

Participants

6

Reactant 5

HCID 962Water2×HCID 6342AcetonitrileHCID 24412Potassium PersulfateHCID 24823Ozone2×HCID 19601787HCID 19601787, compound

Product 1

HCID 57285646HCID 57285646, compound

Procedure

Potassium monopersulfate (4.0 g), water (50 ml), and acetonitrile, (15 ml), were mixed together to form a solution. Then, ozone was added until the solution was saturated. A second solution of 1,3,5,7-tetra-aminocubane hydrochloride in water, 200 mg in 15 ml, was slowly added to the first solution while ozone was slowly bubbled through the first solution. The reaction temperature was 0 degrees C. The addition of ozone was stopped after 2 hours; the reaction mixture was stirred overnight and 10 ml of acetone were added.

Workup

  1. customto form a solution
  2. customwas slowly bubbled through the first solution
  3. customwas 0 degrees C
  4. additionThe addition of ozone
  5. addition10 ml of acetone were added

Sources & evidence

ORD record
ord-f96cafc75aa843e6aa3e75aba45ff89a
Source dataset
uspto-grants-1999_12
Patent number
US05998661

Reaction notes

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