1-Naphthaldehyde → NSC46721

HRID 612957Notes

Reaction equation

[C:1]1([CH:11]=O)[C:10]2[C:5](=[CH:6][CH:7]=[CH:8][CH:9]=2)[CH:4]=[CH:3][CH:2]=1.[C:13]([O-:16])(=[O:15])C.[K+].[C:18](OC(=O)C)(=O)C>>[C:1]1([C:11](=[CH2:18])[C:13]([OH:16])=[O:15])[C:10]2[C:5](=[CH:6][CH:7]=[CH:8][CH:9]=2)[CH:4]=[CH:3][CH:2]=1

Participants

Reactant 3

HCID 61951-Naphthaldehyde

HCID 7918Acetic Anhydride

HCID 517044Potassium Acetate

Product 1

HCID 240501NSC46721Yield 58%

Procedure

1-Naphthaldehyde (30.5 g), potassium acetate (38.3 g) and acetic anhydride (36.9 ml) were subjected to reaction and post-treatment in a similar manner to that described in Reference example 14(a) to obtain the title compound (22.4 g, 58%) as a colorless powder.

Sources & evidence

ORD record: ord-0952328bb47c4484b20b78114c520aba
Source dataset: uspto-grants-1999_12
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US06005116

Reaction notes

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