Hydrogen Peroxide → HCID 53853208, compound

HRID 615405Notes

Reaction equation

HRID 615405 reaction equation
CO[C:3]1[CH:8]=[CH:7][C:6]([C:9]2[C:18]3[C:13](=[CH:14][CH:15]=[CH:16][CH:17]=3)[N:12]=[C:11]([C:19]([OH:21])=[O:20])[CH:10]=2)=[CH:5][CH:4]=1.CC1C=C(C2C=CC=C([N+:39]([O-:41])=[O:40])C=2)C2C(=CC=CC=2)N=1.[Se](=O)=O.OO>>[N+:39]([C:4]1[CH:5]=[C:6]([C:9]2[C:18]3[C:13](=[CH:14][CH:15]=[CH:16][CH:17]=3)[N:12]=[C:11]([C:19]([OH:21])=[O:20])[CH:10]=2)[CH:7]=[CH:8][CH:3]=1)([O-:41])=[O:40]

Participants

5

Reactant 4

HCID 784Hydrogen PeroxideHCID 24007Selenium DioxideHCID 53821249HCID 53821249, compoundHCID 53948822HCID 53948822, compound

Product 1

HCID 53853208HCID 53853208, compound

Procedure

4-(3-nitro phenyl) quinoline 2-carboxylic acid is prepared by analogy as 4-(4-methoxy phenyl) quinoline 2-carboxylic acid described in Example 36 starting from 2-methyl 4-(3-nitro phenyl) quinoline (2.46 10-2 mole), 2.73 g of selenium dioxide and 20.9 ml H2O2 110 vol.

Sources & evidence

ORD record
ord-a32f26a6cae246488a2f08313d1da3b5
Source dataset
uspto-grants-1985_02
Patent number
US04499094

Reaction notes

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