Acetic acid, 2-(triphenylphosphoranylidene)-, methyl ester → HCID 53812018, compound

HRID 615508Notes

Reaction equation

HRID 615508 reaction equation
[CH3:1][C:2]1[CH:3]=[C:4]([CH:7]=[CH:8][C:9]=1[O:10][CH3:11])[CH:5]=O.[CH3:12][O:13][C:14](=[O:35])[CH:15]=P(C1C=CC=CC=1)(C1C=CC=CC=1)C1C=CC=CC=1>>[CH3:1][C:2]1[CH:3]=[C:4]([CH:7]=[CH:8][C:9]=1[O:10][CH3:11])[CH:5]=[CH:15][C:14]([O:13][CH3:12])=[O:35]

Participants

3

Reactant 2

HCID 17453Acetic acid, 2-(triphenylphosphoranylidene)-, methyl esterHCID 1229363-Methyl-4-anisaldehyde

Product 1

HCID 53812018HCID 53812018, compound

Procedure

Treatment of 3-methyl-4-methoxybenzaldehyde with methyl(triphenylphosphoranylidene)acetate in a procedure analogous to that described in Example 20, step a. provided methyl 3-methyl-4-methoxycinnamate which was recrystallized from hexane to give white crystals, mp 70°-73° C.

Workup

  1. customprovided methyl 3-methyl-4-methoxycinnamate which was recrystallized from hexane
  2. customto give white crystals, mp 70°-73° C.

Sources & evidence

ORD record
ord-80c60e16939e4bc0b91c90a951f86a7a
Source dataset
uspto-grants-1985_02
Patent number
US04499299

Reaction notes

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