Hydrogen Peroxide → HCID 20369709, compound

HRID 616335Notes

Reaction equation

HRID 616335 reaction equation
OO.[C:3]([O-:11])(=[O:10])[CH:4]([CH2:6][C:7]([O-:9])=[O:8])[OH:5].[CH3:12][S:13][CH2:14][CH2:15][NH3+:16].[CH3:17][S:18][CH2:19][CH2:20][NH3+:21]>CO>[C:3]([O-:11])(=[O:10])[CH:4]([CH2:6][C:7]([O-:9])=[O:8])[OH:5].[CH3:12][S:13]([CH2:14][CH2:15][NH3+:16])=[O:5].[CH3:17][S:18]([CH2:19][CH2:20][NH3+:21])=[O:5]

Participants

4

Reactant 2

HCID 784Hydrogen PeroxideHCID 20369706HCID 20369706, compound

Product 1

HCID 20369709HCID 20369709, compound

Reagents, catalysts & solvents 1

HCID 887MethanolSolvent

Procedure

5.5 ml of H2O2 (30%) are added to a suspension of 11.25 g of 2-methylthio ethylammonium malate in 50 ml of methanol. The temperature is reduced to 30° C during this addition. The solution obtained is agitated for 4 hours. The sulfoxide formed is precipitated by the addition of ethanol while cooling, yielding 11.2 g of a white product melting at 106° C.

Workup

  1. additionThe temperature is reduced to 30° C during this addition
  2. customThe solution obtained

Sources & evidence

ORD record
ord-2198bb6b9b484ddf8ac1c6a6746ee464
Source dataset
uspto-grants-1978_02
Patent number
US04073898

Reaction notes

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