Hydrogen Peroxide → HCID 53662136, compound

HRID 616336Notes

Reaction equation

HRID 616336 reaction equation
[CH2:1]([S:8][CH2:9][CH2:10][NH:11][C:12]([NH2:14])=[O:13])[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1.[OH:15]O>C(O)=O>[CH2:1]([S:8]([CH2:9][CH2:10][NH:11][C:12]([NH2:14])=[O:13])=[O:15])[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1

Participants

4

Reactant 2

HCID 784Hydrogen PeroxideHCID 54086074HCID 54086074, compound

Product 1

HCID 53662136HCID 53662136, compound

Reagents, catalysts & solvents 1

HCID 284Formic AcidSolvent

Conditions

Temperature
30 °C

Procedure

To a solution of 2-benzylthio ethylurea (0.03 mole) in 12 ml of formic acid, there are added 3 ml of H2O2 (110 volumes). The resulting solution is agitated for 2 hours while maintaining the temperature at 30° C. The solution is then concentrated under reduced pressure and the resulting oil residue, taken up in sulfuric ether, solidifies. The product obtained (4.8 g) is crystallized in acetonitrile and has a melting point of 110° C.

Workup

  1. concentrationThe solution is then concentrated under reduced pressure
  2. customThe product obtained (4.8 g)
  3. customis crystallized in acetonitrile

Sources & evidence

ORD record
ord-974db038280a4b0d941cef4ffe08c99c
Source dataset
uspto-grants-1978_02
Patent number
US04073898

Reaction notes

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