Methylamine → HCID 86754449, compound

HRID 617629Notes

Reaction equation

HRID 617629 reaction equation
[CH3:1][NH2:2].[CH3:3][O:4][N:5]=[C:6]([C:26](=[N:28][O:29][CH3:30])[CH3:27])[C:7](=[N:9][O:10][CH2:11][C:12]1[CH:17]=[CH:16][CH:15]=[CH:14][C:13]=1[CH2:18][O:19][N:20]=[CH:21][C:22]([O:24]C)=O)[CH3:8]>O1CCCC1>[CH3:1][NH:2][C:22](=[O:24])[CH:21]=[N:20][O:19][CH2:18][C:13]1[CH:14]=[CH:15][CH:16]=[CH:17][C:12]=1[CH2:11][O:10][N:9]=[C:7]([CH3:8])[C:6](=[N:5][O:4][CH3:3])[C:26](=[N:28][O:29][CH3:30])[CH3:27]

Participants

4

Reactant 2

HCID 6329MethylamineHCID 86754450HCID 86754450, compound

Product 1

HCID 86754449HCID 86754449, compound

Reagents, catalysts & solvents 1

HCID 8028TetrahydrofuranSolvent

Procedure

2 ml of 40% strength aqueous methylamine solution are added to a solution of 0.6 g (1.5 mmol) of methyl [2-(2,3-bismethoxyimino-1-methylbutylideneaminooxymethyl)phenyl]methoxyiminoacetate in 10 ml of tetrahydrofuran, and the mixture is stirred for 12 hours at room temperature. For working up, the reaction mixture is evaporated in vacuo, taken up in 20 ml of diethyl ether, washed using 20 ml of water, dried over sodium sulfate and evaporated in vacuo. This gives 0.6 g (98%) of an oil.

Workup

  1. customthe reaction mixture is evaporated in vacuo
  2. washwashed
  3. dry with materialdried over sodium sulfate
  4. customevaporated in vacuo

Sources & evidence

ORD record
ord-71bebe7eba8f45f18cfd6a86467f3b9d
Source dataset
uspto-grants-1999_09
Patent number
US05948932

Reaction notes

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