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HRID6204

反应详情

EQUATION

反应方程式

HRID 6204 的结构方程式

REACTANTS

反应物

2
结构：c1ccc(P(c2ccccc2)c2ccccc2)cc1
HCID11776

Triphenylphosphine

C18H15P

结构：O=S(=O)(c1ccc(CBr)cc1)C(F)(F)F
HCID15323598

1-(Bromomethyl)-4-(trifluoromethanesulfonyl)benzene

C8H6BrF3O2S

PRODUCTS

生成物

1
结构：O=S(=O)(c1ccc(C[P+](c2ccccc2)(c2ccccc2)c2ccccc2)cc1)C(F)(F)F.[Br-]
HCID19795088

未命名化合物

AUXILIARIES

试剂、催化剂与溶剂

1
结构：Cc1ccccc1C
溶剂HCID7237

o-Xylene

C8H10

PROCEDURE

实验过程

A solution of 30.3 g (0.1 mole) of 4-triflyl-alpha-bromotoluene and 28.8 g (0.1 mole) of triphenylphosphine in xylene is heated at reflux for 19 hours. 4-Triflylbenzyltriphenylphosphonium bromide is then isolated by filtration, washed with additional portions of xylene, and dried.

WORKUP

后处理

  1. temperatureat reflux for 19 hours