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HRID624220

反应详情

EQUATION

反应方程式

HRID 624220 的结构方程式

REACTANTS

反应物

1
结构：O=C(NCC1CCOC1)OCc1ccccc1
HCID86665085

未命名化合物

PRODUCTS

生成物

2
结构：O=C(NC[C@H]1CCOC1)OCc1ccccc1
HCID86665083

未命名化合物

结构：O=C(NC[C@@H]1CCOC1)OCc1ccccc1
HCID86665084

Carbamic acid, N-[[(3S)-tetrahydro-3-furanyl]methyl]-, phenylmethyl ester

C13H17NO3

AUXILIARIES

试剂、催化剂与溶剂

1
结构：C1CCOC1
溶剂HCID8028

Tetrahydrofuran

C4H8O

PROCEDURE

实验过程

A racemic mixture of benzyl (tetrahydrofuran-3-yl)methylcarbamate was dissolved in tetrahydrofuran and separated by liquid chromatography with a Chiralpak IC 2.5 cm ID×25 cm, 20 micron column, eleuting with hexane/tetrahydrofuran/isopropanol (85/10/5), to provide (R)-benzyl (tetrahydrofuran-3-yl)methylcarbamate and (S)-benzyl (tetrahydrofuran-3-yl)methylcarbamate.

WORKUP

后处理

  1. customseparated by liquid chromatography with a Chiralpak IC 2.5 cm ID×25 cm, 20 micron column