Carbon Dioxide → HCID 58568207, compound

HRID 626291Notes

Reaction equation

HRID 626291 reaction equation
[O:1]1[CH2:7][CH:2]1[C:3]([O:5][CH3:6])=[O:4].[I-].[K+].[C:10](=[O:12])=[O:11]>[Br-].C([N+](CCCC)(CCCC)CCCC)CCC.COC(C)(C)C>[CH3:6][O:5][C:3]([CH:2]1[CH2:7][O:1][C:10](=[O:11])[O:12]1)=[O:4]

Participants

6

Reactant 3

HCID 280Carbon DioxideHCID 4875Potassium IodideHCID 145751Methyl oxirane-2-carboxylate

Product 1

HCID 58568207HCID 58568207, compoundYield 79%

Reagents, catalysts & solvents 2

HCID 74236Tetrabutylammonium BromideCatalystHCID 15413tert-Butyl methyl etherSolvent2×

Procedure

20 g of methyl epoxypropionate were mixed with 20 g of tert-butyl methyl ether, 1.5 g of tetrabutylammonium bromide and 1.5 g of potassium iodide. The homogeneous mixture was transferred to a 100 ml pressurized reactor and carboxylated for 6 days at 50° C. and a CO2 pressure of 30 bar. After the carboxylation, a two-phase system was obtained; the upper phase consisted of tert-butyl methyl ether, and the lower phase consisted of 4-methoxycarbonyl-2-oxo-1,3-dioxolane (purity 83% (GC), yield 79%).

Workup

  1. customAfter the carboxylation, a two-phase system was obtained

Sources & evidence

ORD record
ord-7a077663bb6649ed87b38470d2018a76
Source dataset
uspto-grants-2016_04
Patent number
US09309218B2

Reaction notes

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