Hydrochloric Acid → HCID 21259553, compound

HRID 635547Notes

Reaction equation

HRID 635547 reaction equation
[NH2:1][C:2]1[CH:3]=[C:4]([P:8]([C:16]2[CH:21]=[CH:20][CH:19]=[C:18]([NH2:22])[CH:17]=2)[C:9]2[CH:14]=[CH:13][CH:12]=[C:11]([NH2:15])[CH:10]=2)[CH:5]=[CH:6][CH:7]=1.[ClH:23]>O>[Cl-:23].[Cl-:23].[Cl-:23].[NH3+:1][C:2]1[CH:3]=[C:4]([P:8]([C:16]2[CH:21]=[CH:20][CH:19]=[C:18]([NH3+:22])[CH:17]=2)[C:9]2[CH:14]=[CH:13][CH:12]=[C:11]([NH3+:15])[CH:10]=2)[CH:5]=[CH:6][CH:7]=1

Participants

4

Reactant 2

HCID 313Hydrochloric AcidHCID 12591421HCID 12591421, compound

Product 1

HCID 21259553HCID 21259553, compoundYield 78%

Reagents, catalysts & solvents 1

HCID 962WaterSolvent

Procedure

An aqueous solution of 3.04 g (9.90 mmol) of tris(3-aminophenyl)phosphine in 100 ml of water was treated with 13.5 ml of hydrochloric acid (2 N) and the clear solution was stirred at room temperature for 30 minutes. The solvent was distilled off at 60° C. under reduced pressure, giving 3.21 g of tris(3-ammoniophenyl)phosphine trichloride as a colorless solid (yield: 78%).

Workup

  1. distillationThe solvent was distilled off at 60° C. under reduced pressure

Sources & evidence

ORD record
ord-e0c0c39c88914a69b9e3e64b736e86e2
Source dataset
uspto-grants-2001_02
Patent number
US06187953B1

Reaction notes

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