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HRID642425

反应详情

EQUATION

反应方程式

HRID 642425 的结构方程式

REACTANTS

反应物

4
结构：CNCCNC
HCID8070

N,N'-Dimethylethane-1,2-diamine

C4H12N2

结构：Ic1ccccc1
HCID11575

Benzene, iodo-

C6H5I

结构：O=P([O-])([O-])[O-].[K+].[K+].[K+]
HCID62657

Tripotassium phosphate

K3O4P

结构：CCOC(=O)c1[nH]c2ccccc2c1C
HCID593963

Ethyl 3-methyl-1H-indole-2-carboxylate

C12H13NO2

PRODUCTS

生成物

1
结构：CCOC(=O)c1c(C)c2ccccc2n1-c1ccccc1
HCID54519504

未命名化合物

AUXILIARIES

试剂、催化剂与溶剂

1
结构：[Cu][I]
催化剂HCID24350

Copper(1+) iodide; Copper(I) iodide; Cuprous iodide; Cuprous iodide (CuI)

CuI

PROCEDURE

实验过程

Prepared in analogy to that of Example 1(a) from 3-methyl-1H-indole-2-carboxylic acid ethyl ester, iodobenzene, CuI, N,N′-dimethylethylenediamine, and potassium phosphate. 1H NMR (200 MHz, CDCl3): δ (ppm)=7.7-7.0 (m, 9H), 4.15 (q, 2H, J=7.1 Hz), 2.67 (s, 3H), 1.10 (t, 3H, J=7.1 Hz).