HCID 20484852, compound → HCID 20484847, compound

HRID 648084Notes

Reaction equation

HRID 648084 reaction equation
[CH3:1][C:2]1([CH3:17])[C:6]([C:7]([O:9][CH2:10][CH3:11])=[O:8])=[C:5]([CH2:12][C:13]([OH:16])([CH3:15])[CH3:14])N=N1>C(OCC)(=O)C>[CH3:1][C:2]1([CH3:17])[CH:6]([C:7]([O:9][CH2:10][CH3:11])=[O:8])[CH:5]1[CH2:12][C:13]([OH:16])([CH3:15])[CH3:14]

Participants

3

Reactant 1

HCID 20484852HCID 20484852, compound

Product 1

HCID 20484847HCID 20484847, compoundYield 92.9%

Reagents, catalysts & solvents 1

HCID 8857Ethyl AcetateSolvent

Procedure

350 mg of the product of Step D were dissolved in 100 ml of ethyl acetate and an inert gas was bubbled therethrough for 15 minutes and the solution was then irridated with a mercury vapor lamp. After 10 minutes, 33 ml of nitrogen were disengaged and the solution was evaporated to dryness to obtain 290 mg of ethyl 3,3-dimethyl-2-(2-hydroxy-2-methyl-propyl)-cyclopropane-1-carboxylate.

Workup

  1. customan inert gas was bubbled
  2. customthe solution was then irridated with a mercury vapor lamp
  3. waitAfter 10 minutes
  4. customthe solution was evaporated to dryness

Sources & evidence

ORD record
ord-cc3cf56ec6614c1c997473db083e3a90
Source dataset
uspto-grants-1983_10
Patent number
US04410721

Reaction notes

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