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HRID651304

反应详情

EQUATION

反应方程式

HRID 651304 的结构方程式

REACTANTS

反应物

5
结构：c1ccc(P(c2ccccc2)c2ccccc2)cc1
HCID11776

Triphenylphosphine

C18H15P

结构：N#Cc1ccccc1O
HCID11907

2-Hydroxybenzonitrile

C7H5NO

结构：CCCCCC[C@H](C)O
HCID2723888

2-Octanol, (2S)-

C8H18O

结构：CCOC(=O)/N=N/C(=O)OCC
HCID5462977

(E)-Diethyl azodicarboxylate

C6H10N2O4

结构：CCCCCCCCOC(=O)c1ccc(-c2ccc(OC(=O)OC)cc2)cc1
HCID18328376

未命名化合物

PRODUCTS

生成物

1
结构：CCCCCC[C@@H](C)Oc1ccccc1C#N
HCID21308782

未命名化合物

PROCEDURE

实验过程

Quantities: 2-(hydroxybenzonitrile (38) (9.17 g, 0.077 mol), (S)-(+)-octan-2-ol (10.00 g, 0.077 mol), DEAD (13.41 g, 0.077 mol), triphenylphosphine (20.20 g, 0.077 mol). The experimental procedure was as described for the preparation of compound 5. The crude product was purified by column chromatography (20% petrol/dichloromethane) to give a colourless oil.

WORKUP

后处理

  1. customThe crude product was purified by column chromatography (20% petrol/dichloromethane)
  2. customto give a colourless oil