1-Adamantanecarboxylic acid → 1-Adamantanol

HRID 651363Notes

Reaction equation

HRID 651363 reaction equation
[C:1]12(C(O)=O)[CH2:10][CH:5]3[CH2:6][CH:7]([CH2:9][CH:3]([CH2:4]3)[CH2:2]1)[CH2:8]2.[Mn]([O-])(=O)(=O)=[O:15].[K+]>[OH-].[Na+]>[C:1]12([OH:15])[CH2:10][CH:5]3[CH2:6][CH:7]([CH2:9][CH:3]([CH2:4]3)[CH2:2]1)[CH2:8]2

Participants

4

Reactant 2

HCID 132351-Adamantanecarboxylic acidHCID 516875Potassium Permanganate

Product 1

HCID 641521-Adamantanol

Reagents, catalysts & solvents 1

HCID 14798Sodium HydroxideCatalyst

Procedure

Adamantane-1-carboxylic acid and potassium permanganate were reacted by oxidation using sodium hydroxide as a catalyst to obtain adamantan-1-ol, 4-carboxylic acid.

Sources & evidence

ORD record
ord-40682d88b81c4621968f07eed65e016e
Source dataset
uspto-grants-2001_08
Patent number
US06280897B1

Reaction notes

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