Hydrochloric Acid → HCID 19889695, compound

HRID 653658Notes

Reaction equation

HRID 653658 reaction equation
[CH3:1][C:2]1[C:11]([CH3:12])=[CH:10][CH:9]=[CH:8][C:3]=1[O:4][CH2:5][C:6]#N.[CH2:13]([NH:16][CH2:17][CH2:18][NH2:19])[CH:14]=[CH2:15].[Na+].S.[ClH:22]>>[ClH:22].[CH2:13]([N:16]1[CH2:17][CH2:18][N:19]=[C:6]1[CH2:5][O:4][C:3]1[CH:8]=[CH:9][CH:10]=[C:11]([CH3:12])[C:2]=1[CH3:1])[CH:14]=[CH2:15]

Participants

5

Reactant 4

HCID 313Hydrochloric AcidHCID 520997N-AllylethylenediamineHCID 54638531344-08-7HCID 14878245HCID 14878245, compound

Product 1

HCID 19889695HCID 19889695, compound

Procedure

4.84 g (30 mmol) of 2,3-dimethylphenoxy-acetonitrile, 3.3 g (33 mmol) of N-allyl-ethylenediamine and 260 mg of sodium polysulfide (Na2S4) are stirred together at 50° C. for 4 hours. The excess amine is then stripped off under a high vacuum, ethanolic hydrochloric acid is added to the residue and the hydrochloride is precipitated by addition of ether.

Workup

  1. additionis added to the residue
  2. customthe hydrochloride is precipitated by addition of ether

Sources & evidence

ORD record
ord-44bf345db3df4d0b8759a9afae04ae5f
Source dataset
uspto-grants-1992_07
Patent number
US05128361

Reaction notes

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