Trifluoroacetic acid → HCID 131717454, compound

HRID 653861Notes

Reaction equation

HRID 653861 reaction equation
[CH:1]([NH:3][C@@H:4]1[C:35](=[O:36])[N:6]2[C:7]([C:23]([O:25]CC3C=CC(OC)=CC=3)=[O:24])=[C:8](/[CH:11]=[CH:12]/[CH2:13][N+:14]([C@@H:17]([C:20](=[O:22])[NH2:21])[CH2:18][OH:19])([CH3:16])[CH3:15])[CH2:9][S:10][C@H:5]12)=[O:2].[F:37][C:38]([F:43])([F:42])[C:39]([OH:41])=[O:40]>C1(OC)C=CC=CC=1>[F:37][C:38]([F:43])([F:42])[C:39]([O-:41])=[O:40].[CH:1]([NH:3][C@@H:4]1[C:35](=[O:36])[N:6]2[C:7]([C:23]([OH:25])=[O:24])=[C:8](/[CH:11]=[CH:12]/[CH2:13][N+:14]([C@@H:17]([C:20](=[O:22])[NH2:21])[CH2:18][OH:19])([CH3:15])[CH3:16])[CH2:9][S:10][C@H:5]12)=[O:2]

Participants

4

Reactant 2

HCID 6422Trifluoroacetic acidHCID 14621678HCID 14621678, compound

Product 1

HCID 131717454HCID 131717454, compound

Reagents, catalysts & solvents 1

HCID 7519AnisoleSolvent

Procedure

In a similar manner as in Example 5, the compound (4.98 g) of Example 28 was suspended in anisole (30 ml), followed by an addition of trifluoroacetic acid (33 ml) to obtain the target compound (4.03 g).

Sources & evidence

ORD record
ord-35e733ca22c945d0b5c3381c7e5505e7
Source dataset
uspto-grants-1992_07
Patent number
US05128465

Reaction notes

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