Salicylaldehyde → HCID 5370692, compound

HRID 655064Notes

Reaction equation

HRID 655064 reaction equation
[CH3:1][O:2][C:3](=[O:14])/[C:4](/C)=[CH:5]/[C:6]1[CH:11]=[CH:10][CH:9]=[CH:8][C:7]=1[OH:12].[CH2:15](OC(=O)C=P(C1C=CC=CC=1)(C1C=CC=CC=1)C1C=CC=CC=1)C.C(=O)C1C(=CC=CC=1)O>>[CH2:1]([O:2][C:3](=[O:14])/[CH:4]=[CH:5]/[C:6]1[CH:11]=[CH:10][CH:9]=[CH:8][C:7]=1[OH:12])[CH3:15]

Participants

4

Reactant 3

HCID 6998SalicylaldehydeHCID 70670Acetic acid, 2-(triphenylphosphoranylidene)-, ethyl esterHCID 21490383HCID 21490383, compound

Product 1

HCID 5370692HCID 5370692, compound

Procedure

According to the procedure of Example 1, (E)-3-(2-hydroxy-phenyl)-2-methyl-acrylic acid methyl ester was prepared from ethyl(triphenyl-phosphoranylidene)acetate and salicylaldehyde.

Sources & evidence

ORD record
ord-f0032cb2ca2f49baaf32a258af17868d
Source dataset
uspto-grants-2011_12
Patent number
USRE043006E1

Reaction notes

Loading…