Hydrogen Peroxide → HCID 58150864, compound

HRID 659911Notes

Reaction equation

HRID 659911 reaction equation
Cl.[NH2:2][C:3]1[C:4]([Cl:11])=[C:5]([OH:10])[C:6]([CH3:9])=[CH:7][CH:8]=1.Cl.Cl.[CH2:14]([N:19]([CH2:27][CH2:28][CH2:29][CH2:30][CH3:31])[C:20]1[CH:25]=[CH:24][C:23]([NH2:26])=[CH:22][CH:21]=1)[CH2:15][CH2:16][CH2:17][CH3:18].[OH-].[NH4+].OO>O.C(O)C>[NH2:2][C:3]1[C:8](=[N:26][C:23]2[CH:22]=[CH:21][C:20]([N:19]([CH2:27][CH2:28][CH2:29][CH2:30][CH3:31])[CH2:14][CH2:15][CH2:16][CH2:17][CH3:18])=[CH:25][CH:24]=2)[CH:7]=[C:6]([CH3:9])[C:5](=[O:10])[C:4]=1[Cl:11]

Participants

7

Reactant 4

HCID 784Hydrogen PeroxideHCID 14923Ammonium HydroxideHCID 157640Phenol, 3-amino-2-chloro-6-methyl-, hydrochlorideHCID 66923973HCID 66923973, compound

Product 1

HCID 58150864HCID 58150864, compoundYield 72.4%

Reagents, catalysts & solvents 2

HCID 702EthanolSolventHCID 962WaterSolvent

Procedure

0.48 g of 3-amino-2-chloro-6-methylphenol hydrochloride is added to 0.8 g of N,N-dipentylbenzene-1,4-diamine dihydrochloride in solution in 5 ml of water and 40 ml of ethanol. The pH is adjusted to 9.5 with 20% ammonium hydroxide and then 1.7 ml of 9% aqueous hydrogen peroxide solution are added. The mixture is left stirring at ambient temperature for 5 hours and then the precipitate formed is filtered off. 0.72 g of 3-amino-2-chloro-4-{[4-(dipentylamino)phenyl]imino}-6-methylcyclohexa-2,5-dien-1-one (1o) is thus obtained.

Workup

  1. waitThe mixture is left
  2. customthe precipitate formed
  3. filtrationis filtered off

Sources & evidence

ORD record
ord-ddd7a968db1c45f5b19a33b963685e10
Source dataset
uspto-grants-2011_12
Patent number
US08083809B2

Reaction notes

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