Ammonia → Benzophenone imine

HRID 66084Notes

Reaction equation

HRID 66084 reaction equation
[C:1]([C:9]1[CH:14]=[CH:13][CH:12]=[CH:11][CH:10]=1)(=O)[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1.C(O)(=O)C1C=CC=CC=1.[NH3:24]>ClC1C=CC=CC=1Cl>[C:1](=[NH:24])([C:9]1[CH:14]=[CH:13][CH:12]=[CH:11][CH:10]=1)[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1

Participants

5

Reactant 3

HCID 222AmmoniaHCID 243Benzoic AcidHCID 3102Benzophenone

Product 1

HCID 136809Benzophenone imineYield 26%

Reagents, catalysts & solvents 1

HCID 72391,2-DichlorobenzeneSolvent

Procedure

36.2 Grams of benzophenone, 50 ml of o-dichlorobenzene and 0.5 g of benzoic acid were fed to a reactor. Ammonia gas was passed through the reaction mixture under 6 atmospheres at 160° C. of the reaction temperature at a feed rate of 0.2 l/min. (NTP) continuously. The reaction was conducted for 3 hours and benzophenoneimine was obtained in yield of 26%.

Workup

  1. customwas passed through the reaction mixture under 6 atmospheres at 160° C. of the reaction temperature at a feed rate of 0.2 l/min. (NTP)

Sources & evidence

ORD record
ord-94d6e3ff66d74ae5a525ed7bb123c0c7
Source dataset
uspto-grants-1978_12
Patent number
US04130586

Reaction notes

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