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HRID66097

反应详情

EQUATION

反应方程式

HRID 66097 的结构方程式

REACTANTS

反应物

4
结构：BrCCCCBr
HCID8056

1,4-Dibromobutane

C4H8Br2

结构：O=C([O-])[O-].[K+].[K+]
HCID11430

Potassium Carbonate

CK2O3

结构：[Na+].[OH-]
HCID14798

Sodium Hydroxide

HNaO

结构：Cc1cc(N)cc(C)c1OC12CC3CC(CC(C3)C1)C2.Cl
HCID20342224

未命名化合物

PRODUCTS

生成物

1
结构：Cc1cc(N2CCCC2)cc(C)c1OC12CC3CC(CC(C3)C1)C2
HCID12510314

未命名化合物

AUXILIARIES

试剂、催化剂与溶剂

2
结构：CCO
溶剂HCID702

Ethanol

C2H6O

结构：O
溶剂HCID962

Water

H2O

PROCEDURE

实验过程

The amine obtained by washing a CH2Cl2 solution of 2.1 g. (6.82 mmole) of 4-(1-adamantyloxy)-3,5-dimethylaniline hydrochloride with three 25 ml. portions of 10% aq. NaOH followed by a water wash, drying (anhydrous MgSO4) and concentration, was combined with 1.47 g. (6.82 mmole) of 1,4-dibromobutane and 2.07 g. (15.0 mmole) of K2CO3 in 20 ml. of absolute ethanol and refluxed for approximately 18 hours.

WORKUP

后处理

  1. washby washing a CH2Cl2 solution of 2.1 g
  2. washwash
  3. customdrying
  4. concentration(anhydrous MgSO4) and concentration