N-(1-Methyldecyl)-3-(3-Nitrophenyl)-2-butenamide → HCID 54502184, compound

HRID 66813Notes

Reaction equation

HRID 66813 reaction equation
[CH3:1][CH:2]([NH:12][C:13](=[O:26])[CH:14]=[C:15]([C:17]1[CH:22]=[CH:21][CH:20]=[C:19]([N+:23]([O-])=O)[CH:18]=1)[CH3:16])[CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH3:11]>C(O)(=O)C.[Fe]>[CH3:1][CH:2]([NH:12][C:13](=[O:26])[CH:14]=[C:15]([C:17]1[CH:22]=[CH:21][CH:20]=[C:19]([NH2:23])[CH:18]=1)[CH3:16])[CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH3:11]

Participants

4

Reactant 1

HCID 53905448N-(1-Methyldecyl)-3-(3-Nitrophenyl)-2-butenamide

Product 1

HCID 54502184HCID 54502184, compound

Reagents, catalysts & solvents 2

HCID 23925IronCatalystHCID 176Acetic AcidSolvent

Procedure

The N-(1-methyldecyl)-3-(3-nitrophenyl)-2-butenamide from Preparation 23 (6.5 g.) was reduced with iron powder (5.0 g.) in glacial acetic acid (80 ml.) in a manner analogously to Preparation 27. After chromatography, 4.5 g. of the title compound was obtained, as an amber oil.

Sources & evidence

ORD record
ord-d96bdb1a6b4e4da1912ceaee73b6dc48
Source dataset
uspto-grants-1982_08
Patent number
US04343813

Reaction notes

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