Dimethylformamide → 2-{4-[(1-Ethoxycarbonyl-ethoxy)-methoxy-phosphoryl]-but-2-enyl}-6-[6-methoxy-7-methyl-3-oxo-4-(2-trimethylsilanyl-ethoxy)-1,3-dihydro-isobenzofuran-5-yl]-4-methyl-hex-4-enoic acid 2-trimethylsilanyl-ethyl Ester
Reaction equation
[C:78]([CH:79]([OH:80])[CH3:81])(=[O:82])[O:83][CH2:84][CH3:85].[CH3:1][Si:2]([CH2:3][CH2:4][O:5][C:6]([CH:7]([CH2:8][C:9](=[CH:10][CH2:11][c:12]1[c:13]([O:25][CH2:26][CH2:27][Si:28]([CH3:29])([CH3:30])[CH3:31])[c:14]2[c:18]([c:19]([CH3:23])[c:20]1[O:21][CH3:22])[CH2:17][O:16][C:15]2=[O:24])[CH3:32])[CH2:33][CH:34]=[CH:35][CH2:36][P:37](=[O:38])([O:39][CH3:40])[OH:41])=[O:42])([CH3:43])[CH3:44].[CH:86]([N:87]([CH2:88][CH3:89])[CH:90]([CH3:91])[CH3:92])([CH3:93])[CH3:94].[O:95]=[CH:96][N:97]([CH3:98])[CH3:99].[P-:45]([F:46])([F:47])([F:48])([F:49])([F:50])[F:51].[n:52]1([O:53][P+:54]([N:55]2[CH2:56][CH2:57][CH2:58][CH2:59]2)([N:60]2[CH2:61][CH2:62][CH2:63][CH2:64]2)[N:65]2[CH2:66][CH2:67][CH2:68][CH2:69]2)[c:70]2[cH:71][cH:72][cH:73][cH:74][c:75]2[n:76][n:77]1>>[CH3:1][Si:2]([CH2:3][CH2:4][O:5][C:6]([CH:7]([CH2:8][C:9](=[CH:10][CH2:11][c:12]1[c:13]([O:25][CH2:26][CH2:27][Si:28]([CH3:29])([CH3:30])[CH3:31])[c:14]2[c:18]([c:19]([CH3:23])[c:20]1[O:21][CH3:22])[CH2:17][O:16][C:15]2=[O:24])[CH3:32])[CH2:33][CH:34]=[CH:35][CH2:36][P:37](=[O:38])([O:39][CH3:40])[O:41][CH:79]([C:78](=[O:82])[O:83][CH2:84][CH3:85])[CH3:81])=[O:42])([CH3:43])[CH3:44]Participants
7
Reactant 6
HCID 6228Dimethylformamide
HCID 7344Ethyl Lactate
HCID 9886Hexafluorophosphate
HCID 81531Diisopropylethylamine
HCID 2724700Benzotriazol-1-yl-oxytripyrrolidinophosphonium
HCID 765461902-[4-(Hydroxy-methoxy-phosphoryl)-but-2-enyl]-6-[6-methoxy-7-methyl-3-oxo-4-(2-trimethylsilanyl-ethoxy)-1,3-dihydro-isobenzofuran-5-yl]-4-methyl-hex-4-enoic acid 2-trimethylsilanyl-ethyl esterProduct 1
Sources & evidence
- ORD record
- ord-d8ed7a613b1d4d368933d0b8e8052744
- Source dataset
- Training data from https://doi.org/10.1039/C8SC04228D (3/10)
Reaction notes
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