Catechol → (-)-5-Decyloxy-2-[4-(6-hydroxyheptenyl)phenyl]pyrimidine
Reaction equation
[BH3:35].[CH2:1]([CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH3:10])[O:11][c:12]1[cH:13][n:14][c:15](-[c:18]2[cH:19][cH:20][c:21]([Br:24])[cH:22][cH:23]2)[n:16][cH:17]1.[CH2:44]1[O:45][CH2:46][CH2:47][CH2:48]1.[CH3:127][c:128]1[cH:129][cH:130][cH:131][cH:132][cH:133]1.[Na+:26].[OH-:25].[OH2:126].[OH:27][CH:28]([CH2:29][CH2:30][CH2:31][C:32]#[CH:33])[CH3:34].[c:36]1([OH:43])[c:37]([OH:42])[cH:38][cH:39][cH:40][cH:41]1.[cH:49]1[cH:50][cH:51][c:52]([P:53]([Pd:54]([P:55]([c:56]2[cH:57][cH:58][cH:59][cH:60][cH:61]2)([c:62]2[cH:63][cH:64][cH:65][cH:66][cH:67]2)[c:68]2[cH:69][cH:70][cH:71][cH:72][cH:73]2)([P:74]([c:75]2[cH:76][cH:77][cH:78][cH:79][cH:80]2)([c:81]2[cH:82][cH:83][cH:84][cH:85][cH:86]2)[c:87]2[cH:88][cH:89][cH:90][cH:91][cH:92]2)[P:93]([c:94]2[cH:95][cH:96][cH:97][cH:98][cH:99]2)([c:100]2[cH:101][cH:102][cH:103][cH:104][cH:105]2)[c:106]2[cH:107][cH:108][cH:109][cH:110][cH:111]2)([c:112]2[cH:113][cH:114][cH:115][cH:116][cH:117]2)[c:118]2[cH:119][cH:120][cH:121][cH:122][cH:123]2)[cH:124][cH:125]1>>[CH2:1]([CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH3:10])[O:11][c:12]1[cH:13][n:14][c:15](-[c:18]2[cH:19][cH:20][c:21]([CH:33]=[CH:32][CH2:31][CH2:30][CH2:29][CH:28]([OH:27])[CH3:34])[cH:22][cH:23]2)[n:16][cH:17]1Participants
11
Reactant 10
Product 1
Sources & evidence
- ORD record
- ord-33c26e2161264dde859656ed022ad048
- Source dataset
- Training data from https://doi.org/10.1039/C8SC04228D (3/10)
Reaction notes
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