Tetrahydrofuran → 17-(6-hydroxy-6-methylheptan-2-yl)-10,13-dimethyl-2,3,4,9,11,12,14,15,16,17-decahydro-1H-cyclopenta[a]phenanthrene-1,3-diol
Reaction equation
[Al+3:44].[CH3:1][C:2]([CH3:3])([CH2:4][CH2:5][CH2:6][CH:7]([CH3:8])[CH:9]1[CH2:10][CH2:11][CH:12]2[C:13]3=[CH:14][CH:15]=[C:16]4[CH2:17][CH:18]([OH:28])[CH:19]=[CH:20][C:21]4([CH3:22])[CH:23]3[CH2:24][CH2:25][C:26]12[CH3:27])[OH:29].[H-:43].[H-:46].[H-:47].[H-:48].[Li+:45].[O:49]1[CH2:50][CH2:51][CH2:52][CH2:53]1.[c:30]1([N:31]2[C:32](=[O:41])[N:33]=[N:34][C:35]2=[O:36])[cH:37][cH:38][cH:39][cH:40][cH:42]1>>[CH3:1][C:2]([CH3:3])([CH2:4][CH2:5][CH2:6][CH:7]([CH3:8])[CH:9]1[CH2:10][CH2:11][CH:12]2[C:13]3=[CH:14][CH:15]=[C:16]4[CH2:17][CH:18]([OH:28])[CH2:19][CH:20]([OH:41])[C:21]4([CH3:22])[CH:23]3[CH2:24][CH2:25][C:26]12[CH3:27])[OH:29]Participants
7
Reactant 6
Product 1
Sources & evidence
- ORD record
- ord-a17c9afb68ea4b3981993c3bd344c20f
- Source dataset
- Training data from https://doi.org/10.1039/C8SC04228D (3/10)
Reaction notes
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