Indole → 9-Methyl-6-triisopropylsilanyloxy-1,3,4,9-tetrahydro-beta-carboline-2-carboxylic acid tert-butyl ester
Reaction equation
[C:1]([CH3:2])([CH3:3])([CH3:4])[O:5][C:6](=[O:7])[N:8]1[CH2:9][c:10]2[nH:11][c:12]3[cH:13][cH:14][c:15]([O:21][Si:22]([CH:23]([CH3:24])[CH3:25])([CH:26]([CH3:27])[CH3:28])[CH:29]([CH3:30])[CH3:31])[cH:16][c:17]3[c:18]2[CH2:19][CH2:20]1.[CH2:67]([O:68][CH2:69][CH3:70])[CH3:71].[CH3:32][C:33]([CH3:34])([O-:35])[CH3:36].[I:56][CH3:57].[K+:37].[O:38]1[CH2:39][CH2:40][O:41][CH2:42][CH2:43][O:44][CH2:45][CH2:46][O:47][CH2:48][CH2:49][O:50][CH2:51][CH2:52][O:53][CH2:54][CH2:55]1.[nH:58]1[c:59]2[c:60]([cH:61][cH:62][cH:63][cH:64]2)[cH:65][cH:66]1>>[C:1]([CH3:2])([CH3:3])([CH3:4])[O:5][C:6](=[O:7])[N:8]1[CH2:9][c:10]2[n:11]([CH3:32])[c:12]3[cH:13][cH:14][c:15]([O:21][Si:22]([CH:23]([CH3:24])[CH3:25])([CH:26]([CH3:27])[CH3:28])[CH:29]([CH3:30])[CH3:31])[cH:16][c:17]3[c:18]2[CH2:19][CH2:20]1Participants
8
Reactant 7
Product 1
Sources & evidence
- ORD record
- ord-257deb08bb114f73ab76f0b8af4a5765
- Source dataset
- Training data from https://doi.org/10.1039/C8SC04228D (3/10)
Reaction notes
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