Bromide ion → (4-Nitro-1H-indol-3-yl)-(2,2,3,3-tetramethyl-cyclopropyl)-methanone

HRID 686185Notes

Reaction equation

HRID 686185 reaction equation
[Br-:13].[CH2:14]([Mg+:15])[CH3:16].[CH3:17][C:18]1([CH3:26])[CH:19]([C:23](=[O:24])[Cl:25])[C:20]1([CH3:21])[CH3:22].[Cl-:30].[Cl-:32].[Cl:27][CH2:28][Cl:29].[N+:1](=[O:2])([O-:3])[c:4]1[c:5]2[cH:6][cH:7][nH:8][c:9]2[cH:10][cH:11][cH:12]1.[Zn+2:31]>>[N+:1](=[O:2])([O-:3])[c:4]1[c:5]2[c:6]([C:23]([CH:19]3[C:18]([CH3:17])([CH3:26])[C:20]3([CH3:21])[CH3:22])=[O:24])[cH:7][nH:8][c:9]2[cH:10][cH:11][cH:12]1

Participants

8

Reactant 7

HCID 259Bromide ionHCID 312Chloride2×HCID 6344DichloromethaneHCID 32051Zinc(2+)HCID 1457664-Nitro-1H-indoleHCID 110410022,2,3,3-Tetramethylcyclopropane-1-carbonyl chlorideHCID 178461628HCID 178461628, compound

Product 1

HCID 24823929(4-Nitro-1H-indol-3-yl)-(2,2,3,3-tetramethyl-cyclopropyl)-methanone

Sources & evidence

ORD record
ord-f55f0e5f77dd4ffb88af74d39fa27500
Source dataset
Training data from https://doi.org/10.1039/C8SC04228D (3/10)

Reaction notes

Loading…