proline dl-form → HCID 86699380, compound

HRID 688308Notes

Reaction equation

HRID 688308 reaction equation
[Br:1][c:2]1[cH:3][c:4]([CH:8]2[CH2:9][N:10]([CH3:20])[CH2:11][c:12]3[c:13]([Cl:19])[cH:14][c:15]([Cl:18])[cH:16][c:17]32)[cH:5][cH:6][cH:7]1.[C:44](=[O:45])([O-:46])[O-:47].[CH3:50][S:51]([CH3:52])=[O:53].[Cu:55][I:56].[K+:48].[K+:49].[N:21](=[N+:22]=[N-:23])[CH2:24][CH2:25][O:26][CH2:27][CH2:28][O:29][CH2:30][CH2:31][O:32][CH2:33][CH2:34][NH2:35].[NH:36]1[CH2:37][CH2:38][CH2:39][CH:40]1[C:41]([OH:42])=[O:43].[OH2:54]>>[c:2]1([NH:35][CH2:34][CH2:33][O:32][CH2:31][CH2:30][O:29][CH2:28][CH2:27][O:26][CH2:25][CH2:24][N:21]=[N+:22]=[N-:23])[cH:3][c:4]([CH:8]2[CH2:9][N:10]([CH3:20])[CH2:11][c:12]3[c:13]([Cl:19])[cH:14][c:15]([Cl:18])[cH:16][c:17]32)[cH:5][cH:6][cH:7]1

Participants

9

Reactant 8

HCID 614proline dl-formHCID 679Dimethyl SulfoxideHCID 813Potassium Cation2×HCID 962WaterHCID 19660Carbonate IonHCID 24350Copper(1+) iodide; Copper(I) iodide; Cuprous iodide; Cuprous iodide (CuI)HCID 27352801-Amino-11-azido-3,6,9-trioxaundecaneHCID 223869034-(3-Bromophenyl)-6,8-dichloro-2-methyl-1,2,3,4-tetrahydroisoquinoline

Product 1

HCID 86699380HCID 86699380, compound

Sources & evidence

ORD record
ord-5dc31a62c3a943e79922cb1f0bedb8fe
Source dataset
Training data from https://doi.org/10.1039/C8SC04228D (3/10)

Reaction notes

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