Potassium Cation → 2,10-dichloro-12H-dibenzo[d,g][1,3]dioxocine

HRID 692316Notes

Reaction equation

HRID 692316 reaction equation
[C:21](=[O:22])([O-:23])[O-:24].[Cl:1][c:2]1[cH:3][cH:4][c:5]([OH:17])[c:6]([CH2:8][c:9]2[c:10]([OH:16])[cH:11][cH:12][c:13]([Cl:15])[cH:14]2)[cH:7]1.[I:18][CH2:19][I:20].[K+:25].[K+:26].[O:28]=[CH:29][N:30]([CH3:31])[CH3:32].[OH2:27]>>[Cl:1][c:2]1[cH:3][cH:4][c:5]2[c:6]([cH:7]1)[CH2:8][c:9]1[c:10]([cH:11][cH:12][c:13]([Cl:15])[cH:14]1)[O:16][CH2:19][O:17]2

Participants

7

Reactant 6

HCID 813Potassium Cation2×HCID 962WaterHCID 3037DichlorophenHCID 6228DimethylformamideHCID 6346DiiodomethaneHCID 19660Carbonate Ion

Product 1

HCID 149005562,10-dichloro-12H-dibenzo[d,g][1,3]dioxocine

Sources & evidence

ORD record
ord-7b7b927555f74269aadf2faf8d6b74db
Source dataset
Training data from https://doi.org/10.1039/C8SC04228D (3/10)

Reaction notes

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