Methanol → Methyl 3-(hydroxymethyl)-5-nitrobenzoate

HRID 700607Notes

Reaction equation

HRID 700607 reaction equation
[BH3:27].[CH3:1][O:2][C:3](=[O:4])[c:5]1[cH:6][c:7]([C:8](=[O:9])[OH:10])[cH:11][c:12]([N+:14](=[O:15])[O-:16])[cH:13]1.[CH3:28][OH:29].[CH3:30][CH2:31][O:32][C:33](=[O:34])[CH3:35].[O:17]1[CH2:18][CH2:19][CH2:20][CH2:21]1.[O:22]1[CH2:23][CH2:24][CH2:25][CH2:26]1>>[CH3:1][O:2][C:3](=[O:4])[c:5]1[cH:6][c:7]([CH2:8][OH:9])[cH:11][c:12]([N+:14](=[O:15])[O-:16])[cH:13]1

Participants

6

Reactant 5

HCID 887MethanolHCID 6331BoraneHCID 8028Tetrahydrofuran2×HCID 8857Ethyl AcetateHCID 747761,3-Benzenedicarboxylic acid, 5-nitro-, 1-methyl ester

Product 1

HCID 10703703Methyl 3-(hydroxymethyl)-5-nitrobenzoate

Sources & evidence

ORD record
ord-effc9d47596e4907888bed59afec5cc1
Source dataset
Training data from https://doi.org/10.1039/C8SC04228D (3/10)

Reaction notes

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