Acetate → Methyl 2-(diphenylphosphanyl)benzoate

HRID 701916Notes

Reaction equation

HRID 701916 reaction equation
[C:42]([O-:43])(=[O:44])[CH3:45].[C:47]([O-:48])(=[O:49])[CH3:50].[CH3:32][CH2:33][N:34]([CH2:35][CH3:36])[CH2:37][CH3:38].[CH3:39][C:40]#[N:41].[F:14][C:15]([F:16])([F:17])[S:18]([O:19][c:20]1[c:21]([C:22](=[O:23])[O:24][CH3:25])[cH:26][cH:27][cH:28][cH:29]1)(=[O:30])=[O:31].[Pd+2:46].[c:1]1([PH:7][c:8]2[cH:9][cH:10][cH:11][cH:12][cH:13]2)[cH:2][cH:3][cH:4][cH:5][cH:6]1>>[c:1]1([P:7]([c:8]2[cH:9][cH:10][cH:11][cH:12][cH:13]2)[c:20]2[c:21]([C:22](=[O:23])[O:24][CH3:25])[cH:26][cH:27][cH:28][cH:29]2)[cH:2][cH:3][cH:4][cH:5][cH:6]1

Participants

7

Reactant 6

HCID 175Acetate2×HCID 6342AcetonitrileHCID 8471TriethylamineHCID 70017DiphenylphosphineHCID 105144Allyl(1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene)chloropalladium(II)HCID 11011497methyl 2-trifluoromethanesulfonyloxybenzoate

Product 1

HCID 13741333Methyl 2-(diphenylphosphanyl)benzoate

Sources & evidence

ORD record
ord-f65aa5bd84a740f0b541b51d915d67fa
Source dataset
Training data from https://doi.org/10.1039/C8SC04228D (3/10)

Reaction notes

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