Tetrabutylammonium Hydroxide → 1-Butanaminium, N,N,N-tributyl-, methyl carbonate (1:1)

HRID 713375Notes

Reaction equation

HRID 713375 reaction equation
[OH-].[CH2:2]([N+:6]([CH2:15][CH2:16][CH2:17][CH3:18])([CH2:11][CH2:12][CH2:13][CH3:14])[CH2:7][CH2:8][CH2:9][CH3:10])[CH2:3][CH2:4][CH3:5].[CH3:19][O:20][C:21](=[O:23])[O-:22]>CO>[CH3:19][O:20][C:21](=[O:22])[O-:23].[CH2:15]([N+:6]([CH2:2][CH2:3][CH2:4][CH3:5])([CH2:7][CH2:8][CH2:9][CH3:10])[CH2:11][CH2:12][CH2:13][CH3:14])[CH2:16][CH2:17][CH3:18]

Participants

4

Reactant 2

HCID 2723671Tetrabutylammonium HydroxideHCID 4585885Methylcarbonate

Product 1

HCID 111416611-Butanaminium, N,N,N-tributyl-, methyl carbonate (1:1)

Reagents, catalysts & solvents 1

HCID 887MethanolSolvent

Procedure

As above, 30 g of a 40% b.w. solution of tetrabutylammonium hydroxide (46.0 mmole base) in methanol was mixed with 45 g DMC. After decantation of some precipitate, a clear solution of 0.68 meq methylcarbonate per g solution was obtained.

Workup

  1. customwas obtained

Sources & evidence

ORD record
ord-17db886c70da4599ae7c771aa8031604
Source dataset
uspto-grants-2015_11
Patent number
US09181452B2

Reaction notes

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