Isatoic Anhydride → N-isoprenyl isatoic anhydride

HRID 716680Notes

Reaction equation

[C:1]12[C:7](=[CH:8][CH:9]=[CH:10][CH:11]=1)[NH:6][C:5](=[O:12])[O:4][C:2]2=[O:3].[H-].[Na+].[CH:15](Br)=[CH:16][C:17](=[CH2:19])[CH3:18]>>[CH:15]([N:6]1[C:5](=[O:12])[O:4][C:2](=[O:3])[C:1]2=[CH:11][CH:10]=[CH:9][CH:8]=[C:7]12)=[CH:16][C:17](=[CH2:18])[CH3:19]

Participants

Reactant 3

HCID 8359Isatoic Anhydride

HCID 24758Sodium hydride

HCID 53976308Bromoisoprene

Product 1

HCID 131734149N-isoprenyl isatoic anhydride

Procedure

Reagents: Isatoic anhydride (6.13 mmols, 1 g); Sodium hydride (9.2 mmols, 0.23 g); Isoprenyl bromide (12 mmols, 1.9 g). Yield: 0.95 g (67%), white solid, m.p.=119° C.-120° C.

Sources & evidence

ORD record: ord-a156aeb4fb5b461da904b7748364092e
Source dataset: uspto-grants-2015_11
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US09193688B2

Reaction notes

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