1-Octene → HCID 21895230, compound

HRID 720766Notes

Reaction equation

HRID 720766 reaction equation
[C:1]1([PH:7](=[O:15])[O:8][CH:9]2[CH2:14][CH2:13][CH2:12][CH2:11][CH2:10]2)[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1.[CH2:16]=[CH:17][CH2:18][CH2:19][CH2:20][CH2:21][CH2:22][CH3:23]>C1(C)C=CC=CC=1>[C:1]1([P:7](/[CH:16]=[CH:17]/[CH2:18][CH2:19][CH2:20][CH2:21][CH2:22][CH3:23])(=[O:15])[O:8][CH:9]2[CH2:14][CH2:13][CH2:12][CH2:11][CH2:10]2)[CH:2]=[CH:3][CH:4]=[CH:5][CH:6]=1

Participants

4

Reactant 2

HCID 81251-OcteneHCID 178527039HCID 178527039, compound

Product 1

HCID 21895230HCID 21895230, compoundYield 98%

Reagents, catalysts & solvents 1

HCID 1140TolueneSolvent

Procedure

In toluene (2 ml)under a nitrogen atmosphere at 100° C. for 20 hours, 1 mmol of cyclohexyl phenylphosphinate and 1 mmol of 1-octene were allowed to react using 3 molar % of Rh(PPh3)3Br as a catalyst to give cyclohexyl phenyl[(E)-1-octen-1-yl]phosphinate in a yield of 98%.

Workup

  1. customto react

Sources & evidence

ORD record
ord-51fb554d2f124358bf4afe1bbb6a8f91
Source dataset
uspto-grants-2006_11
Patent number
US07135583B2

Reaction notes

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