Benzaldehyde → HCID 67136987, compound

HRID 723367Notes

Reaction equation

HRID 723367 reaction equation
[O:1]([C:8]1[CH:13]=[CH:12][C:11]([NH:14][NH2:15])=[CH:10][CH:9]=1)[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1.[CH:16](=O)[C:17]1[CH:22]=[CH:21][CH:20]=[CH:19][CH:18]=1>CO>[CH:16](=[N:15][NH:14][C:11]1[CH:12]=[CH:13][C:8]([O:1][C:2]2[CH:3]=[CH:4][CH:5]=[CH:6][CH:7]=2)=[CH:9][CH:10]=1)[C:17]1[CH:22]=[CH:21][CH:20]=[CH:19][CH:18]=1

Participants

4

Reactant 2

HCID 240BenzaldehydeHCID 2760972(4-phenoxyphenyl)hydrazine

Product 1

HCID 67136987HCID 67136987, compound

Reagents, catalysts & solvents 1

HCID 887MethanolSolvent

Procedure

A suspension of (4-phenoxyphenyl)hydrazine (J. Org. Chem. 1956, 395; 1.5 g) in methanol (10 mL) was mixed with benzaldehyde (0.76 mL) and heated to reflux. The crystals which separated out on cooling were filtered off with suction. The product with the molecular weight of 288.35 (C19H16N2O); MS (ESI): 289 ([M+H]+), was obtained in this way.

Workup

  1. temperatureheated to reflux
  2. customThe crystals which separated out
  3. temperatureon cooling
  4. filtrationwere filtered off with suction
  5. customMS (ESI): 289 ([M+H]+), was obtained in this way

Sources & evidence

ORD record
ord-559485146324438eaa0a475c3a734b00
Source dataset
uspto-grants-2006_11
Patent number
US07141561B2

Reaction notes

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