Oxygen → 2-Octanone

HRID 726896Notes

Reaction equation

HRID 726896 reaction equation
[CH2:1]=[CH:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH3:8].[O:9]=O>C=CCCCCCC.C(O)CC.O.Cl[Pd]Cl>[CH2:6]([C:7]([CH3:8])=[O:9])[CH2:5][CH2:4][CH2:3][CH2:2][CH3:1]

Participants

7

Reactant 2

HCID 977OxygenHCID 81251-Octene

Product 1

HCID 80932-Octanone

Reagents, catalysts & solvents 4

HCID 962WaterCatalystHCID 10311-PropanolCatalystHCID 81251-OcteneCatalystHCID 24290Palladium ChlorideCatalyst

Procedure

The autoclave described above was charged with 17 g of ME containing 1-octene as compound to be oxidized and having the following composition (in % by weight including catalyst): 54% of 1-octene, 7.7% of Igepal, 1.9% of Triton 100, 19.2% of n-propanol, 10.7% of water and 0.8% of PdCl2 /5.7% of Fe(NO3)3 as catalyst. The oxidation was carried out for 6 hours at 50° C. and 1 bar using pure oxygen. Methyl hexyl ketone was obtained as product. The selectivity was 54% at a conversion of 14%.

Workup

  1. additionabove was charged with 17 g of ME

Sources & evidence

ORD record
ord-8873271c27b24e86b9913f193ce2711b
Source dataset
uspto-grants-1998_01
Patent number
US05710342

Reaction notes

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