Methane → HCID 11805083, compound

HRID 727471Notes

Reaction equation

HRID 727471 reaction equation
[N+:1]([C:4]1[CH:9]=[CH:8][CH:7]=[CH:6][CH:5]=1)([O-])=O.[CH3:10][C:11](=O)[CH2:12][CH3:13].[CH4:15].[H][H]>[Pt]>[CH:11]([NH:1][C:4]1[CH:9]=[CH:8][C:7]([CH3:15])=[CH:6][CH:5]=1)([CH2:12][CH3:13])[CH3:10]

Participants

6

Reactant 4

HCID 297MethaneHCID 6569Methyl Ethyl KetoneHCID 7416NitrobenzeneHCID 178418361HCID 178418361, compound

Product 1

HCID 11805083HCID 11805083, compound

Reagents, catalysts & solvents 1

HCID 23939PlatinumCatalyst

Procedure

411 g (3 mol) of 4-nitrobenzene, 238 g (3.3 mol) of butan-2-one and 8 g of a platinum catalyst on activated charcoal (sulfited; 50% moisture content) are placed in an autoclave (volume: 2 liters) fitted with a reciprocating stirrer, and are reacted at 100° C. under a hydrogen pressure of 10 bar, with stirring. When the uptake of hydrogen has ceased (after a reaction time of 5.5 hours), the mixture is cooled, the autoclave is depressurized and the catalyst is filtered off.

Workup

  1. customfitted with a reciprocating stirrer
  2. customare reacted at 100° C. under a hydrogen pressure of 10 bar
  3. customafter a reaction time of 5.5 hours
  4. temperatureis cooled
  5. filtrationthe catalyst is filtered off

Sources & evidence

ORD record
ord-5f99aea60315497ebd2ad6b96b454f29
Source dataset
uspto-grants-1998_01
Patent number
US05712414

Reaction notes

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