1-Butanol → Zirconium butoxide

HRID 727988Notes

Reaction equation

HRID 727988 reaction equation
[CH2:1]([OH:5])[CH2:2][CH2:3][CH3:4].[Zr:6].O>C(O)CC.CC(O)C>[CH3:4][CH2:3][CH2:2][CH2:1][O-:5].[CH3:4][CH2:3][CH2:2][CH2:1][O-:5].[CH3:4][CH2:3][CH2:2][CH2:1][O-:5].[CH3:4][CH2:3][CH2:2][CH2:1][O-:5].[Zr+4:6]

Participants

6

Reactant 3

HCID 2631-ButanolHCID 962WaterHCID 23995Zirconium

Product 1

HCID 160560Zirconium butoxide

Reagents, catalysts & solvents 2

HCID 10311-PropanolSolvent2×HCID 3776IsopropanolSolvent

Procedure

1 butanol (171.6 gm) was mixed with 125 ml of n-propanol and placed in a one liter, three-neck round-bottom flask under nitrogen atmosphere. The concentration of zirconium was 0.95 molar. A solution of 28.8 ml of deionized water in 125 ml of n-propanol was added through an addition funnel under nitrogen atmosphere to the solution in the flask with rapid stirring for two minutes. The stirring was stopped, and the mixture was left to stand for three hours. The mixture was then centrifuged, and the mother liquor was discarded. The solid residue was ultrasonically dispersed in 2-propanol and then centrifuged to harvest the supernatant sol. This procedure was repeated several times.

Workup

  1. waitthe mixture was left
  2. waitto stand for three hours

Sources & evidence

ORD record
ord-86d93c301391450cb70c8a9187b58abc
Source dataset
uspto-grants-1991_09
Patent number
US05047174

Reaction notes

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