Triethylamine → HCID 14989153, compound

HRID 728396Notes

Reaction equation

HRID 728396 reaction equation
[CH3:1][C:2]([C:5]1[CH:10]=[C:9]([SH:11])[CH:8]=[C:7]([C:12]([CH3:15])([CH3:14])[CH3:13])[C:6]=1[OH:16])([CH3:4])[CH3:3].Br[CH2:18][C:19](=[O:22])[CH2:20][CH3:21].C(N(CC)CC)C>C(OCC)C>[CH3:4][C:2]([C:5]1[CH:10]=[C:9]([S:11][CH2:18][C:19](=[O:22])[CH2:20][CH3:21])[CH:8]=[C:7]([C:12]([CH3:15])([CH3:14])[CH3:13])[C:6]=1[OH:16])([CH3:1])[CH3:3]

Participants

5

Reactant 3

HCID 8471TriethylamineHCID 131561-Bromo-2-butanoneHCID 703702,6-Di-tert-butyl-4-mercaptophenol

Product 1

HCID 14989153HCID 14989153, compound

Reagents, catalysts & solvents 1

HCID 3283Diethyl EtherSolvent

Procedure

The thiol of Example 2 (7.1 g, 0.03 M) was reacted with 1-bromo-2-butanone (5 g) and triethylamine (4.2 ml) in ethyl ether (25 ml) by the method of Example 8 to give the title compound, m.p. ca. 55-57° C.

Sources & evidence

ORD record
ord-7d84cf65738d4893ae3508e865fc7f12
Source dataset
uspto-grants-1991_09
Patent number
US05047593

Reaction notes

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