Ammonia → HCID 178428277, compound

HRID 729180Notes

Reaction equation

HRID 729180 reaction equation
CS(O)(=O)=O.CS(O)(=O)=O.[NH2:11][C:12]1[C:19](=[O:20])[N:15]2[CH2:16][CH2:17][CH2:18][N:14]2[C:13]=1[NH2:21].[CH3:22][C:23]1[CH:32]=[CH:31][C:30]2[C:25](=[CH:26][CH:27]=[CH:28][CH:29]=2)[C:24]=1[OH:33].N.OO>O.C(O)C>[NH2:21][C:13]1[N:14]2[CH2:18][CH2:17][CH2:16][N:15]2[C:19](=[O:20])[C:12]=1/[N:11]=[C:31]1\[CH:32]=[C:23]([CH3:22])[C:24](=[O:33])[C:25]2[C:30]\1=[CH:29][CH:28]=[CH:27][CH:26]=2

Participants

7

Reactant 4

HCID 222AmmoniaHCID 784Hydrogen PeroxideHCID 240552-Methyl-1-naphtholHCID 715878212,3-Diaminodihydropyrazolo pyrazolone dimethosulfonate

Product 1

HCID 178428277HCID 178428277, compound

Reagents, catalysts & solvents 2

HCID 702EthanolSolventHCID 962WaterSolvent

Procedure

0.58 mmol of 2,3-diamino-6,7-dihydro-1H,5H-pyrazolo[1,2-a]pyrazol-1-one dimethane sulphonate was dissolved in a mixture of water and ethanol (7.5 ml/1.5 ml). This solution was admixed with 0.58 mmol of 2-methyl-1-naphthol, then with 1.8 ml of concentrated aqueous ammonia, then with 9 ml of hydrogen peroxide.

Sources & evidence

ORD record
ord-56c5ca59569d4210984d3c45cfc58b9f
Source dataset
uspto-grants-2009_09
Patent number
US07582123B2

Reaction notes

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