Ammonia → HCID 178428282, compound

HRID 729189Notes

Reaction equation

HRID 729189 reaction equation
CS(O)(=O)=O.[NH2:6][C:7]1[C:8](=[O:19])[N:9]2[CH2:15][CH2:14][N:13]([CH3:16])[CH2:12][CH2:11][N:10]2[C:17]=1[NH2:18].[NH2:20][C:21]1[C:22]([Cl:29])=[C:23]([OH:28])[C:24]([CH3:27])=[CH:25][CH:26]=1.N.OO>O.C(O)C>[NH2:18][C:17]1[N:10]2[CH2:11][CH2:12][N:13]([CH3:16])[CH2:14][CH2:15][N:9]2[C:8](=[O:19])[C:7]=1[N:6]=[C:26]1[CH:25]=[C:24]([CH3:27])[C:23](=[O:28])[C:22]([Cl:29])=[C:21]1[NH2:20]

Participants

7

Reactant 4

HCID 222AmmoniaHCID 784Hydrogen PeroxideHCID 1576415-Amino-6-Chloro-o-CresolHCID 866277388,9-diamino-3-methyl-2,3,4,5-tetrahydro-1H,7H-pyrazolo[1,2-a][1,2,5]triazepin-7-one methanesulfonate

Product 1

HCID 178428282HCID 178428282, compound

Reagents, catalysts & solvents 2

HCID 702EthanolSolventHCID 962WaterSolvent

Procedure

0.32 mmol of 8,9-diamino-3-methyl-2,3,4,5-tetrahydro-1H,7H-pyrazolo[1,2-a][1,2,5]triazepin-7-one methanesulfonate was dissolved in a mixture of water and ethanol (7.5 ml/1.5 ml). This solution was admixed with 0.32 mmol of 3-amino-2-chloro-6-methylphenol, then with 1.8 ml of concentrated aqueous ammonia, then with 9 ml of hydrogen peroxide.

Sources & evidence

ORD record
ord-b6b0efa045aa4f269cba03dbff46ba5c
Source dataset
uspto-grants-2009_09
Patent number
US07582123B2

Reaction notes

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