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HRID73938

反应详情

EQUATION

反应方程式

HRID 73938 的结构方程式

REACTANTS

反应物

2
结构：COC(OC)N(C)C
HCID78373

Methanamine, 1,1-dimethoxy-N,N-dimethyl-

C5H13NO2

结构：CCOC(=O)c1cc([N+](=O)[O-])cc([N+](=O)[O-])c1C
HCID43386560

未命名化合物

PRODUCTS

生成物

1
结构：CCOC(=O)c1cc([N+](=O)[O-])cc([N+](=O)[O-])c1C=CN(C)C
HCID76548813

未命名化合物

收率 48%

AUXILIARIES

试剂、催化剂与溶剂

1
结构：CN(C)C=O
溶剂HCID6228

N,N-Dimethylformamide

C3H7NO

CONDITIONS

反应条件

温度
100 °C

PROCEDURE

实验过程

A mixture of 2-methyl-3,5-dinitro-benzoic acid ethyl ester (35 g, 0.14 mol) and dimethoxymethyl-dimethyl-amine (32 g, 0.27 mol) in DMF (200 mL) was heated at 100° C. for 5 h. The mixture was poured into ice-water. The precipitate was collected via filtration and washed with water to give 2-(2-dimethylamino-vinyl)-3,5-dinitro-benzoic acid ethyl ester (11.3 g, 48%).

WORKUP

后处理

  1. filtrationThe precipitate was collected via filtration
  2. washwashed with water